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Aluminum isopropoxide → N2,N5-Diacetyl-L-ornithine

HRID 597281
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HRID 597281 반응식
[OH-].[Mg+2:2].[OH-].[C:4]([NH:7][C@H:8]([C:16]([OH:18])=[O:17])[CH2:9][CH2:10][CH2:11][NH:12][C:13](=[O:15])[CH3:14])(=[O:6])[CH3:5].CC(C)[O-].[Al+3:23].CC(C)[O-].CC(C)[O-]>O.C(O)(C)C>[Mg:2].[Al:23].[C:4]([NH:7][C@H:8]([C:16]([OH:18])=[O:17])[CH2:9][CH2:10][CH2:11][NH:12][C:13](=[O:15])[CH3:14])(=[O:6])[CH3:5]
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참가 물질

7

반응물 3

HCID 11143Aluminum isopropoxideHCID 65977N2,N5-Diacetyl-L-ornithineHCID 73981Magnesium Hydroxide

생성물 2

HCID 65977N2,N5-Diacetyl-L-ornithine수율 404.7%HCID 10129885Aluminium magnesium alloy powder

시약·촉매·용매 2

HCID 962Water
용매
2회
HCID 3776Isopropanol용매

반응 조건

온도
60 °C

실험 절차

Magnesium hydroxide (11.66 g.; 0.2 mole) suspended in water (20 cc.) is added to N,N'-diacetylornithine (172.8 g.; 0.8 mole) dissolved in distilled water (1,200 cc.) at 60° C. The reaction mixture is heated and stirred at 60° C for 30 minutes. Aluminium isopropoxide (81.6 g.; 0.4 mole) suspended in isopropanol (100 cc.) is added, and the mixture is then stirred and heated at 60° C for 30 minutes. After treatment of the reaction mixture as in Example 1, a mixed aluminium magnesium salt of N,N'-diacetyl-ornithine (175 g.) is obtained in the form of a white powder corresponding to the formula: ##EQU6## Al% = 5.45 (theory: 5.35) and Mg% = 2.36 (theory: 2.42).

후처리

  1. temperatureThe reaction mixture is heated
  2. additionis added
  3. stirringthe mixture is then stirred
  4. temperatureheated at 60° C for 30 minutes

출처 및 근거

ORD 기록
ord-643c527a22c64811b5b6bf2e4cd50170
출처 데이터셋
uspto-grants-1977_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04013699

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