Sulfanium bromide → Sulfonium perfluorobutane sulfonate

HRID 597756노트

반응식

HRID 597756 반응식
[Br-].[SH3+:2].[F:3][C:4]([F:19])([S:15]([O-:18])(=[O:17])=[O:16])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[Na+]>[N+](C)([O-])=O>[F:19][C:4]([F:3])([S:15]([O-:18])(=[O:17])=[O:16])[C:5]([F:13])([F:14])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[SH3+:2]

참가 물질

4

반응물 2

HCID 23498378Sulfanium bromideHCID 23678450Sodium perfluorobutanesulfonate

생성물 1

HCID 22483813Sulfonium perfluorobutane sulfonate

시약·촉매·용매 1

HCID 6375Nitromethane용매

실험 절차

The thus obtained monomer precursor is mixed with, for example, phenacyl bromide in acetonitrile or nitromethan at room temperature, to thereby obtain the corresponding sulfonium bromide. With the thus obtained sulfonium bromide, for example, sodium perfluorobutane sulfonate is mixed in nitromethane at room temperature to thereby obtain the targeted product of sulfonium perfluorobutane sulfonate. Moreover, the thus obtained sulfonium perfluorobutanesulfonate can be further purified by recrystallization.

출처 및 근거

ORD 기록
ord-b7f149b3e99a4d5aabb5b4e532189636
출처 데이터셋
uspto-grants-2011_03
특허 번호
US07897321B2

반응 노트

불러오는 중…