p-Tolylacetonitrile → HCID 73053005, 화합물

HRID 59832

반응식

[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[N:14]([C:15]3[CH:20]=[CH:19][C:18]([CH3:21])=[CH:17][CH:16]=3)[N:13]=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)([O-])=[O:2].[C:22]1([CH3:31])[CH:27]=[CH:26][C:25]([CH2:28]C#N)=[CH:24][CH:23]=1>>[C:22]1([CH3:31])[CH:27]=[CH:26][C:25]([C:28]2[O:2][N:1]=[C:4]3[CH:9]=[CH:8][C:7]([C:10]4[N:14]([C:15]5[CH:16]=[CH:17][C:18]([CH3:21])=[CH:19][CH:20]=5)[N:13]=[CH:12][CH:11]=4)=[CH:6][C:5]=23)=[CH:24][CH:23]=1

참가 물질

반응물 2

HCID 76280p-Tolylacetonitrile

HCID 900328535-(4-nitro-phenyl)-1 p-tolyl-1H-pyrazole2회

생성물 1

HCID 73053005HCID 73053005, 화합물

실험 절차

The title compound, yellow solid (35 mg, 27%), MS (ISP) m/z=366.2 [(M+H)+], mp 190° C., was prepared in accordance with the general method of example 1 from 5-(4-nitro-phenyl)-1-p-tolyl-1H-pyrazole (intermediate E) (100 mg, 353 μmol) and commercially available 2-(p-tolyl)-acetonitrile.

출처 및 근거

ORD 기록: ord-ea7f90f6e7774f89b2ecc36d8cdad31b
출처 데이터셋: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09440962B2

연결된 노트

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