p-Tolylacetonitrile → HCID 73053152, 화합물

HRID 59838

반응식

[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([N:9]2[C:13]([C:14]3[CH:19]=[CH:18][C:17]([N+:20]([O-:22])=O)=[CH:16][CH:15]=3)=[CH:12][CH:11]=[N:10]2)=[CH:5][CH:4]=1.[C:23]1([CH3:32])[CH:28]=[CH:27][C:26]([CH2:29]C#N)=[CH:25][CH:24]=1>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([N:9]2[C:13]([C:14]3[CH:19]=[CH:18][C:17]4=[N:20][O:22][C:32]([C:23]5[CH:28]=[CH:27][C:26]([CH3:29])=[CH:25][CH:24]=5)=[C:16]4[CH:15]=3)=[CH:12][CH:11]=[N:10]2)=[CH:5][CH:4]=1

참가 물질

반응물 2

HCID 76280p-Tolylacetonitrile

HCID 90032750HCID 90032750, 화합물2회

생성물 1

HCID 73053152HCID 73053152, 화합물

실험 절차

The title compound, light green solid (32 mg, 25%), MS (ISP) m/z=382.3 [(M+H)+], mp 159° C., was prepared in accordance with the general method of example 1 from 1-(4-methoxy-phenyl)-5-(4-nitro-phenyl)-1H-pyrazole (intermediate G) (100 mg, 353 μmol) and commercially available 2-(p-tolyl)-acetonitrile.

출처 및 근거

ORD 기록: ord-6b395732ddbf4408904a2bacd55df9d4
출처 데이터셋: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09440962B2

연결된 노트

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