1,2,3,4,5,6,7,8-octapropyl-9,10-dihydroanthracene → 1,2,3,4,5,6,7,8-octapropylanthracene

HRID 600131노트

반응식

HRID 600131 반응식
[CH2:1]([C:4]1[C:17]2[CH2:16][C:15]3[C:10](=[C:11]([CH2:27][CH2:28][CH3:29])[C:12]([CH2:24][CH2:25][CH3:26])=[C:13]([CH2:21][CH2:22][CH3:23])[C:14]=3[CH2:18][CH2:19][CH3:20])[CH2:9][C:8]=2[C:7]([CH2:30][CH2:31][CH3:32])=[C:6]([CH2:33][CH2:34][CH3:35])[C:5]=1[CH2:36][CH2:37][CH3:38])[CH2:2][CH3:3]>C1C=CC=CC=1>[CH2:30]([C:7]1[C:8]2[C:17](=[CH:16][C:15]3[C:10]([CH:9]=2)=[C:11]([CH2:27][CH2:28][CH3:29])[C:12]([CH2:24][CH2:25][CH3:26])=[C:13]([CH2:21][CH2:22][CH3:23])[C:14]=3[CH2:18][CH2:19][CH3:20])[C:4]([CH2:1][CH2:2][CH3:3])=[C:5]([CH2:36][CH2:37][CH3:38])[C:6]=1[CH2:33][CH2:34][CH3:35])[CH2:31][CH3:32]

참가 물질

3

반응물 1

HCID 114323181,2,3,4,5,6,7,8-octapropyl-9,10-dihydroanthracene

생성물 1

HCID 114550891,2,3,4,5,6,7,8-octapropylanthracene수율 79.6%

시약·촉매·용매 1

HCID 241Benzene용매

실험 절차

After 2,3-dichloro-5,6-dicyanoquinone (0.100 g, 0.440 mmol) was added to a solution of 1,2,3,4,5,6,7,8-octapropyl-9,10-dihydroanthracene (0.208 g, 0.400 mmol) in benzene (5 ml), the mixture was refluxed for an hour with heating. The reaction mixture was filtered to remove hydroquinone and purified by silica gel column chromatography (ethyl acetate/hexane, 99/1) to give the title compound (0.164 g) as a white solid. The isolation yield was 79%.

후처리

  1. temperaturethe mixture was refluxed for an hour
  2. temperaturewith heating
  3. filtrationThe reaction mixture was filtered
  4. customto remove hydroquinone
  5. custompurified by silica gel column chromatography (ethyl acetate/hexane, 99/1)

출처 및 근거

ORD 기록
ord-8065783f97954cc58ed3954c39c8ddcd
출처 데이터셋
uspto-grants-2011_03
특허 번호
US07901594B2

반응 노트

불러오는 중…