Benzaldehyde → (E)-2-(2-Benzylidenehydrazinyl)benzoic acid

HRID 601162

반응식

HRID 601162 반응식
Cl.[NH:2]([C:4]1[CH:12]=[CH:11][CH:10]=[CH:9][C:5]=1[C:6]([OH:8])=[O:7])[NH2:3].[CH:13](=O)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[CH:13](=[N:3]/[NH:2][C:4]1[CH:12]=[CH:11][CH:10]=[CH:9][C:5]=1[C:6]([OH:8])=[O:7])\[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

참가 물질

3

반응물 2

HCID 240BenzaldehydeHCID 104169Benzoic acid, 2-hydrazinyl-, hydrochloride (1:1)

생성물 1

HCID 9561044(E)-2-(2-Benzylidenehydrazinyl)benzoic acid

실험 절차

The title compound was prepared from 2-hydrazinobenzoic acid hydrochloride (1.89 g, 10.0 mmol) and benzaldehyde (1.06 g, 10.0 mmol) according to the procedure of Fischer, E. and co-workers described in Chem. Ber., 35, 1902, 2318 (2.4 g, quantitative yield). MS (DCI) m/z 241 (M+H)+.

출처 및 근거

ORD 기록
ord-6d1024f6a29240f0b05f02af51dcb53d
출처 데이터셋
uspto-grants-2011_03
특허 번호
US07902203B2

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