Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Mercuric cyanide → 2,4,6-tricyanophenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Mercuric cyanide | HCID 11591 | — |
| 반응물 | 2,3,4-tri-O-acetyl-5-thio-alpha-xylopyranosyl bromide | HCID 10926314 | — |
| 반응물 | 3,5-Dicyano-2-mercaptobenzonitrile | HCID 14795337 | — |
| 생성물 | 2,4,6-tricyanophenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside | HCID 14795365 | 17% |
반응 단계
If the procedure described in Preparation I is followed starting from 4.8 g (258.10-3 mol) of 3,5-dicyano-2-mercaptobenzonitrile (Example 17a), 9.71 g (258.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide and 6.57 g (8.6.10-3 mol) of mercuric cyanide (Hg(CN)2), 2 g (yield: 17%) of the expected product are obtained after crystallization from ether.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05246961 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-20ce36ae2e6848d387fd32a102b78617 |
| 출처 메모 | uspto-grants-1993_09 |