Hydroquinone → 4-[2-Amino-4-(4-bromo-benzyloxy)-phenoxy]-phenol

HRID 607304노트

반응식

[Br:1][C:2]1[CH:19]=[CH:18][C:5]([CH2:6][O:7][C:8]2[CH:13]=[CH:12][C:11](Cl)=[C:10]([N+:15]([O-])=O)[CH:9]=2)=[CH:4][CH:3]=1.[C:20]1([CH:27]=[CH:26][C:24]([OH:25])=[CH:23][CH:22]=1)[OH:21]>>[NH2:15][C:10]1[CH:9]=[C:8]([O:7][CH2:6][C:5]2[CH:18]=[CH:19][C:2]([Br:1])=[CH:3][CH:4]=2)[CH:13]=[CH:12][C:11]=1[O:21][C:20]1[CH:27]=[CH:26][C:24]([OH:25])=[CH:23][CH:22]=1

참가 물질

반응물 2

HCID 785Hydroquinone

HCID 574698834-(4-Bromo-benzyloxy)-1-chloro-2-nitro-benzene

생성물 1

HCID 668085674-[2-Amino-4-(4-bromo-benzyloxy)-phenoxy]-phenol

실험 절차

4-(4-Bromo-benzyloxy)-1-chloro-2-nitro-benzene (from Example 16A) was reacted with hydroquinone according to the procedure from Example 39A and reduced according to the procedure from Example 39B to provide the title product.

출처 및 근거

ORD 기록: ord-70139d9f0f56406b84ad765ca809e475
출처 데이터셋: uspto-grants-2011_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07915411B2

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