Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4-Methoxybenzaldehyde → 8(p-Methoxyphenyl)-7-octennitrile
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4-Methoxybenzaldehyde | HCID 31244 | — |
| 반응물 | 6-Cyanohexyltriphenylphosphonium bromide | HCID 18795089 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 8(p-Methoxyphenyl)-7-octennitrile | HCID 53768714 | 71.1% |
반응 단계
This compound was synthesized from 6-cyanohexyltriphenylphosphonium bromide (9.05 g, 20 mmol) and p-anisaldehyde (2.72 g, 20 mmol) in THF (100 mL) by a Wittig reaction. Kugelrohr distillation afforded the products (3.26 g, 71%) as a colorless liquid (bp: 143-146° C./0.05 torr). IR: 2285 cm-1 ; 1H-NMR: 1.50 (m, 6 H), 2.30 (m, 4 H), 3.80 (s, 3 H), 5.50 (m, 1 H), 6.30 (d, 1 H), 7.05 (q, 4 H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06001869 |
| 출처 데이터셋 | uspto-grants-1999_12 |
| ORD ID | ord-57eb3a890bbd458a89f979423af686ea |
| 출처 메모 | uspto-grants-1999_12 |