2-Bromo-1,1,1-trifluoroethane → HCID 178447772, 화합물

HRID 612335

반응식

HRID 612335 반응식
[Br-].[O:2]([C:10]1[CH:35]=[CH:34][C:13]([CH2:14][P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=[CH:12][CH:11]=1)[Si](C(C)(C)C)(C)C.[CH2:36]([Si:41]1(C2C=CC=CC=2)[CH2:46][CH2:45][CH:44]([CH:47]2[CH2:52][CH2:51][CH:50]([CH:53]=O)[CH2:49][CH2:48]2)[CH2:43][CH2:42]1)[CH2:37][CH2:38][CH2:39][CH3:40].Br[CH2:62][C:63]([F:66])([F:65])[F:64]>>[F:64][C:63]([F:66])([F:65])[CH2:62][O:2][C:10]1[CH:11]=[CH:12][C:13]([CH2:14][CH2:53][C@H:50]2[CH2:51][CH2:52][C@H:47]([C@H:44]3[CH2:45][CH2:46][Si@H:41]([CH2:36][CH2:37][CH2:38][CH2:39][CH3:40])[CH2:42][CH2:43]3)[CH2:48][CH2:49]2)=[CH:34][CH:35]=1

참가 물질

4

반응물 3

HCID 678982-Bromo-1,1,1-trifluoroethaneHCID 103930914-(t-Butyldimethylsiloxy)benzyltriphenylphosphonium bromideHCID 538633044-(4-Phenyl-4-n-pentyl-4-silacyclohexyl)cyclohexane carbaldehyde

생성물 1

HCID 178447772HCID 178447772, 화합물

실험 절차

The general procedure of Example 38 was repeated using 4-(t-butyldimethylsiloxy)benzyltriphenylphosphonium bromide, 4-(4-n-pentyl-4-phenyl-4-silacyclohexyl)cyclohexane carbaldehyde, and 1-bromo-2,2,2-trifluoroethane, thereby obtaining the intended compound.

후처리

  1. customobtaining the intended compound

출처 및 근거

ORD 기록
ord-1e24cbf6d84b40219cfec86ed087f688
출처 데이터셋
uspto-grants-1999_12
특허 번호
US06004478

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