Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,1'-Biphenyl, 3-nitro- → 3-Aminobiphenyl
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,1'-Biphenyl, 3-nitro- | HCID 16450 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Chloroform methanol | HCID 21584188 | — |
| 생성물 | 3-Aminobiphenyl | HCID 16717 | 95% |
반응 단계
A mixture of 3-nitrobiphenyl (20 g, 100 mmol) and 10% Pd/C (2 g) in MeOH/CHCl3 (300 mL, 1:1) is hydrogenated at 40 psi for 4 hours. The mixture is suction filtered through a layer of diatomaceous earth and washed with MeOH. The filtrate is evaporated to dryness and the solid is further dried under vacuum to give 16 g (95%) of 3-aminobiphenyl.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06004536 |
| 출처 데이터셋 | uspto-grants-1999_12 |
| ORD ID | ord-d58c166ee3b949b489661f1f73bb36cb |
| 출처 메모 | uspto-grants-1999_12 |