Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- → 4-Hydroxy-3-[(2-naphthalenylmethyl)thio]-6-phenyl-2H-pyran-2-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- | HCID 117406 | — |
| 반응물 | [(2-Naphthalenylmethyl)thio]propanedioic acid | HCID 19596193 | — |
| 생성물 | 4-Hydroxy-3-[(2-naphthalenylmethyl)thio]-6-phenyl-2H-pyran-2-one | HCID 54681494 | — |
반응 단계
The title compound was prepared by Method A using 1-phenyl-1-(trimethylsilyloxy)ethylene (0.475 g, 2.46 mmol) and dimethyl ester of [(2-naphthalenylmethyl)thio]propanedioic acid (0.500 g, 1.64 mmol). m.p. dec>250° C.; 1H NMR (250 MHz, DMSO-d6) δ4.06 (s, 2 H), 6.47 (s, 1 H), 7.46 (m, 6 H), 7.78 (m, 6 H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06005103 |
| 출처 데이터셋 | uspto-grants-1999_12 |
| ORD ID | ord-cd11143dd647424f8647ff596af96881 |
| 출처 메모 | uspto-grants-1999_12 |