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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 613048생성일: 2026년 10월 26일

Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- → 4-Hydroxy-3-[(2-naphthalenylmethyl)thio]-6-phenyl-2H-pyran-2-one

https://huagongshe.com/reaction/613048

반응식

참여 물질

역할이름HCID투입량
반응물Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-HCID 117406—
반응물[(2-Naphthalenylmethyl)thio]propanedioic acidHCID 19596193—
생성물4-Hydroxy-3-[(2-naphthalenylmethyl)thio]-6-phenyl-2H-pyran-2-oneHCID 54681494—

반응 단계

The title compound was prepared by Method A using 1-phenyl-1-(trimethylsilyloxy)ethylene (0.475 g, 2.46 mmol) and dimethyl ester of [(2-naphthalenylmethyl)thio]propanedioic acid (0.500 g, 1.64 mmol). m.p. dec>250° C.; 1H NMR (250 MHz, DMSO-d6) δ4.06 (s, 2 H), 6.47 (s, 1 H), 7.46 (m, 6 H), 7.78 (m, 6 H).

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US06005103
출처 데이터셋uspto-grants-1999_12
ORD IDord-cd11143dd647424f8647ff596af96881
출처 메모uspto-grants-1999_12