Isoprene → 1-(1,2-Dimethyl-propyl)-4-methyl-cyclohex-3-enecarbaldehyde

HRID 61327

반응식

HRID 61327 반응식
[CH3:1][CH:2]([CH:7]([CH3:9])[CH3:8])[C:3](=[CH2:6])[CH:4]=[O:5].[CH2:10]=[CH:11][C:12](=[CH2:14])[CH3:13]>>[CH3:1][CH:2]([C:3]1([CH:4]=[O:5])[CH2:10][CH2:11][C:12]([CH3:14])=[CH:13][CH2:6]1)[CH:7]([CH3:9])[CH3:8]

참가 물질

3

반응 조건

온도
160 °C

실험 절차

3,4-Dimethyl-2-methylene-pentanal (550 g, obtained as detailed above) and 393 g of isoprene were charged to a Parr Bomb, heated to 160° C., and aged for 12 hours. The rushed over material provided ˜32% recovery of 1-(1,2-dimethyl-propyl)-4-methyl-cyclohex-3-enecarbaldehyde (415 g).

출처 및 근거

ORD 기록
ord-3203e99590bb4da6b11acc7689d1cedd
출처 데이터셋
uspto-grants-2016_09
특허 번호
US09441185B2

연결된 노트

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