Cyclohexane → 1,6-Hexanediol

HRID 613818

반응식

HRID 613818 반응식
[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8].C1CCCCC1>O>[CH2:7]([OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][OH:1].[C:7]1(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1.[CH:7]1([OH:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

참가 물질

5

반응물 2

HCID 8078CyclohexaneHCID 144906-Hydroxyhexanoic Acid

생성물 2

HCID 123741,6-HexanediolHCID 22492587Cyclohexanol cyclohexanone

시약·촉매·용매 1

HCID 962Water용매

실험 절차

1,6-Hexanediol is prepared from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol by water extraction of the reaction mixture, by esterification of the acids and hydrogenation wherein

출처 및 근거

ORD 기록
ord-ec76ee5107f24359a492880185d17646
출처 데이터셋
uspto-grants-1999_12
특허 번호
US06008418

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