(4-Methoxyphenyl)hydrazine → HCID 21329382, 화합물

HRID 614385노트

반응식

HRID 614385 반응식
[S:1]1(=[O:11])(=[O:10])[CH2:8][CH2:7][CH2:6][C:5](=O)[CH2:4][CH2:3][CH2:2]1.[CH3:12][O:13][C:14]1[CH:19]=[CH:18][C:17]([NH:20]N)=[CH:16][CH:15]=1>C(O)(=O)C>[CH3:12][O:13][C:14]1[CH:19]=[CH:18][C:17]2[NH:20][C:5]3[CH2:4][CH2:3][CH2:2][S:1](=[O:11])(=[O:10])[CH2:8][CH2:7][C:6]=3[C:16]=2[CH:15]=1

참가 물질

4

반응물 2

HCID 77023(4-Methoxyphenyl)hydrazineHCID 262584thiocan-5-one 1,1-dioxide

생성물 1

HCID 21329382HCID 21329382, 화합물수율 88%

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

A mixture of 26.54g (0.15 mole) of 1-thiacyclooctane-5-one 1,1-dioxide and 22.0g (0.16 mole) of p-methoxyphenylhydrazine in 150 ml of glacial acetic acid is treated according to the procedure in Example 2. There is obtained 36.7g (88%) of a crystalline solid, m.p. 231°-233° C. Recrystallization from acetone-ethyl acetate gives 30g (72%) of an analytical sample, m.p. 233°-235° C.

후처리

  1. additionis treated

출처 및 근거

ORD 기록
ord-4b36497838684da28a55bd1a7da98e0a
출처 데이터셋
uspto-grants-1979_03
특허 번호
US04144349

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