1,3-Cyclohexanedione → 2-[[2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionyl]]cyclohexane-1,3-dione

HRID 615723

반응식

HRID 615723 반응식
[F:1][C:2]([F:23])([F:22])[C:3]1[CH:21]=[CH:20][C:6]([O:7][C:8]2[CH:19]=[CH:18][C:11]([O:12][CH:13]([CH3:17])[C:14](F)=[O:15])=[CH:10][CH:9]=2)=[CH:5][CH:4]=1.[Tl].[C:25]1(=[O:32])[CH2:30][CH2:29][CH2:28][C:27](=[O:31])[CH2:26]1>CCOCC>[F:1][C:2]([F:23])([F:22])[C:3]1[CH:21]=[CH:20][C:6]([O:7][C:8]2[CH:19]=[CH:18][C:11]([O:12][CH:13]([CH3:17])[C:14]([CH:26]3[C:27](=[O:31])[CH2:28][CH2:29][CH2:30][C:25]3=[O:32])=[O:15])=[CH:10][CH:9]=2)=[CH:5][CH:4]=1

참가 물질

5

반응물 3

HCID 104341,3-CyclohexanedioneHCID 5359464ThalliumHCID 539414602-{4-[4-(Trifluoromethyl)phenoxy]phenoxy}propanoyl fluoride

생성물 1

HCID 133648952-[[2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionyl]]cyclohexane-1,3-dione

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

2-[4-(4-Trifluoromethylphenoxy)phenoxy]propionic acid fluoride (0.10 mol) is added to a solution of the thallium salt of cyclohexane-1,3-dione in ether (200 ml) over a period of 30 minutes. The mixture is filtered and the filtrate is concentrated to give 2-[[2-[4-(4-trifluoromethylphenoxy)phenoxy]propionyl]]cyclohexane-1,3-dione (V; Y is H, Z is CF3, R1 is CH3 and n is two).

후처리

  1. filtrationThe mixture is filtered
  2. concentrationthe filtrate is concentrated

출처 및 근거

ORD 기록
ord-4e9e6f155d8e4f9eac9d292b5940ff22
출처 데이터셋
uspto-grants-1985_02
특허 번호
US04500737

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