Acetyl chloride → (1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane

반응식

[CH3:1][C@@:2]1([OH:14])[CH2:6][CH2:5][C@@H:4]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:3]1([CH3:13])[CH3:12].[C:15](Cl)(=[O:17])[CH3:16]>>[CH3:1][C@@:2]1([O:14][C:15](=[O:17])[CH3:16])[CH2:6][CH2:5][C@@H:4]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:3]1([CH3:13])[CH3:12]

참가 물질

반응물 2

HCID 6367Acetyl chloride

HCID 70474476(1R,S) 1,2,2-trimethyl-3-(2-pentenyl)-cyclopentanol

생성물 1

HCID 70472830(1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane

실험 절차

Using the procedure of Example 15, 2 g of (1R,S) 1,2,2-trimethyl-3-(2-pentenyl)-cyclopentanol and 10 ml of acetyl chloride were reacted to obtain 1.5 g of (1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane.

후처리

customwere reacted

출처 및 근거

ORD 기록: ord-b6b851ff54c842bd8a1dfea1ddb85357
출처 데이터셋: uspto-grants-1985_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04501687

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