Water → 1-Acetamido-2-amino-4-benzylthiobenzene
반응식
[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][C:6]=1[N+:19]([O-])=O)(=[O:3])[CH3:2].O>[Fe].CO>[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][C:6]=1[NH2:19])(=[O:3])[CH3:2]참가 물질
5
실험 절차
2.4 G. of 1-acetamido-2-nitro-4-benzylthiobenzene is treated with 2.4 g. iron powder and 1.2 g. ferrous sulfate in a mixture of 60 ml. water and 240 ml. methanol, at reflux for 4 hours. The mixture is then filtered, the filtrate concentrated and the residue recrystallized from benzene. Pure 1-acetamido-2-amino-4-benzylthiobenzene is obtained.
후처리
- filtrationThe mixture is then filtered
- concentrationthe filtrate concentrated
- customthe residue recrystallized from benzene
출처 및 근거
- ORD 기록
- ord-1b56a93dea7345e5adf1da1fd8c48dbc
- 출처 데이터셋
- uspto-grants-1978_02
- 특허 번호
- US04072696
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