Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Hydroxide → 2-t-Butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | tert-Amyl hydroperoxide | HCID 76962 | — |
| 반응물 | 2-t-Butylazo-2-hydroxy-4-methoxy-4-methylpentane | HCID 20367922 | — |
| 반응물 | (E)-1-tert-Butyl-2-(2-chloro-4-methoxy-4-methylpentan-2-yl)diazene | HCID 23344765 | — |
| 생성물 | 2-t-Butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane | HCID 20367906 | — |
반응 단계
The 2-t-butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane was prepared in 97% crude yield from 7.78 grams (0.0331 moles) of 2-t-butylazo-2-chloro-4-methoxy-4-methylpentane, 5.35 grams (0.0464 moles) of 90% t-amyl hydroperoxide and 7.92 grams (0.0353 moles) of 25% potassium hydroxide solution. The procedure was the same as that described in Example XX. The infrared spectrum of the product indicated there was a small amount of 2-t-butylazo-2-hydroxy-4-methoxy-4-methylpentane present in the product.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04075199 |
| 출처 데이터셋 | uspto-grants-1978_02 |
| ORD ID | ord-dcfe7a064a2a46a49157193b35d6a997 |
| 출처 메모 | uspto-grants-1978_02 |