Nitric Acid → 5-Chloro-4-nitrothiophene-2-sulfonyl chloride
반응식
[Cl:1][C:2]1[S:6][C:5]([S:7]([Cl:10])(=[O:9])=[O:8])=[CH:4][CH:3]=1.[N+:11]([O-])([OH:13])=[O:12]>S(=O)(=O)(O)O>[Cl:1][C:2]1[S:6][C:5]([S:7]([Cl:10])(=[O:9])=[O:8])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12]참가 물질
4
반응 조건
- 온도
- 25 °C
실험 절차
A 32.5-g (0.15 mol) sample of 5-chloro-2-thienylsulfonyl chloride was added in small portions to a stirred solution of 150 ml concentrated nitric acid and 150 ml concentrated sulfuric acid. After the addition was completed, the reaction mixture was stirred at about 25° C overnight. The reaction mixture was then diluted with ice water and filtered to give the 5-chloro-4-nitro-2-thienylsulfonyl chloride product.
후처리
- additionAfter the addition
- filtrationfiltered
출처 및 근거
- ORD 기록
- ord-5f85466c5728470e8f71830812e4e1aa
- 출처 데이터셋
- uspto-grants-1978_02
- 특허 번호
- US04075347
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