Benzoic Acid → Allyl benzoate

HRID 617671

반응식

HRID 617671 반응식
[C:1]([OH:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:10](O)[CH:11]=[CH2:12].S(=O)(=O)(O)O>C1(C)C=CC=CC=1>[C:1]([O:9][CH2:12][CH:11]=[CH2:10])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

5

반응물 3

HCID 243Benzoic AcidHCID 1118Sulfuric AcidHCID 7858Allyl Alcohol

생성물 1

HCID 11406Allyl benzoate

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

To a 250 mL round bottom flask equipped with a reflux condensor was added 25 g of benzoic acid, 51 g of allyl alcohol, and 2.5 g of sulfuric acid. The mixture was heated at reflux for 17 hr, allowed to cool to room temperature, and 50 g of toluene was added. Using a 1 L separatory funnel, the mixture was washed once with 100 mL of water, once with 50 mL of 5 wt % Na2CO3 in water, and once more with 100 mL of water. The organic phase was dried over Na2SO4, filtered and distilled to yield allyl benzoate. The allyl benzoate distilled at a boiling point of 135° C. at about 60 mm Hg.

후처리

  1. customTo a 250 mL round bottom flask equipped with a reflux condensor
  2. temperatureThe mixture was heated
  3. temperatureat reflux for 17 hr
  4. washthe mixture was washed once with 100 mL of water, once with 50 mL of 5 wt % Na2CO3 in water
  5. dry with materialThe organic phase was dried over Na2SO4
  6. filtrationfiltered
  7. distillationdistilled

출처 및 근거

ORD 기록
ord-5af5111cff34414da1315fd62ac2d55b
출처 데이터셋
uspto-grants-1999_09
특허 번호
US05951912

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