Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → Sebacic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Cyclodecane | HCID 9267 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 생성물 | Sebacic Acid | HCID 5192 | 48% |
| 생성물 | Cyclodecanone | HCID 73918 | 39% |
| 생성물 | Sebacil | HCID 96839 | 5% |
반응 단계
A mixture of 1.40 grams (10 millimoles) of cyclodecane, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide, 0.015 gram (0.06 millimole) of Co(AA)2 and 25 milliliters of acetic acid was stirred in an oxygen atmosphere at a temperature of 100° C. for six hours. As a result, cyclodecane was transformed into cyclodecanone (yield 39%), sebacic acid (yield 48%) and cyclodecanedione (yield 5%) with a transformation rate of 96%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05958821 |
| 출처 데이터셋 | uspto-grants-1999_09 |
| ORD ID | ord-dce6f015c3404477a537c72a080277ea |
| 출처 메모 | uspto-grants-1999_09 |