Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → Cyclooctene-3-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 반응물 | 1-Cyclooctene | HCID 13609 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | 2-Cycloocten-1-ol | HCID 98328 | 15% |
| 생성물 | Cyclooctene-3-one | HCID 137176 | 78% |
반응 단계
A mixture of 1.10 grams (10 millimoles) of cyclooctene, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide, 0.021 gram (0.06 millimole) of acetylacetonatocobalt Co(AA)2 and 25 milliliters of acetonitrile was stirred in an oxygen atmosphere at a temperature of 100° C. for 6 hours. The product in the reaction mixture was analyzed with gas chromatography. Cyclooctene was transformed, with a transformation rate of 95%, into 2-cycloocten-1-one (cyclooctene-based selectivity 82%, yield 78%) and 2-cycloocten-1-ol (cyclooctene-based selectivity 16%, yield 15%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05958821 |
| 출처 데이터셋 | uspto-grants-1999_09 |
| ORD ID | ord-5629545e6ea04bcdaa5d4c52c2efc6e4 |
| 출처 메모 | uspto-grants-1999_09 |