Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → 2-Pinanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Pinane | HCID 10129 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | 2-Pinanol | HCID 10128 | 82% |
반응 단계
To 25 milliliters of acetonitrile were added 1.38 grams (10 millimoles) of pinane, 0.13 gram (0.8 millimole) of N-hydroxyphthalimide and 0.015 gram (0.06 millimole) of Co(AA)2, and the resultant mixture was stirred in an oxygen atmosphere at a temperature of 100° C. for six hours. Pinane was transformed into 2-pinanol (selectivity for pinane 91%, yield 82%) with a transformation rate of 90%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05958821 |
| 출처 데이터셋 | uspto-grants-1999_09 |
| ORD ID | ord-2d1f307dec764a8ead7ab279d21b9f11 |
| 출처 메모 | uspto-grants-1999_09 |