Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(1-Chloroethyl)benzene → 1-(3-Vinylphenyl)-1-phenylethane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (1-Chloroethyl)benzene | HCID 12648 | — |
| 반응물 | HCID 178436337 | HCID 178436337 | — |
| 생성물 | 1-(3-Vinylphenyl)-1-phenylethane | HCID 14750258 | — |
반응 단계
(1-Chloroethyl)benzene (formula VI) is subjected to coupling reaction with a Grignard reagent of 3-vinylphenylmagnesium bromide (formula VII) in the presence of a catalyst of nickel chloride (II)-diphosphine complex, to obtain 1-(3-vinylphenyl)-1-phenylethane. The reaction is carried out in a nitrogen atmosphere under atmospheric pressure at a temperature of 0° to 80° C. The ratio of (VI)/(VII) may be in the range of about 1.0 to 1.5. ##STR9##
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04822934 |
| 출처 데이터셋 | uspto-grants-1989_04 |
| ORD ID | ord-c751cc797d1948abb698a6f491abf4ef |
| 출처 메모 | uspto-grants-1989_04 |