HCID 86740397, 화합물 → HCID 86740410, 화합물

HRID 621097노트

반응식

HRID 621097 반응식
ClCC([NH:5][C:6]1[S:7][CH:8]=[C:9]([C:11](=[N:26][O:27][CH3:28])[C:12]([NH:14][C@H:15]2[C@H:18]([S:19][CH3:20])[N:17]([S:21]([O-:24])(=[O:23])=[O:22])[C:16]2=[O:25])=[O:13])[N:10]=1)=O.[Na+:29].CSC(=S)N.[Na]>O>[NH2:5][C:6]1[S:7][CH:8]=[C:9]([C:11](=[N:26][O:27][CH3:28])[C:12]([NH:14][C@H:15]2[C@H:18]([S:19][CH3:20])[N:17]([S:21]([O-:24])(=[O:23])=[O:22])[C:16]2=[O:25])=[O:13])[N:10]=1.[Na+:29]

참가 물질

4

반응물 2

HCID 86740397HCID 86740397, 화합물HCID 86740411HCID 86740411, 화합물

생성물 1

HCID 86740410HCID 86740410, 화합물수율 45%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

To a solution of 0.15 g of the above-mentioned sodium (3R,4S)-3-[2-(2-chloroacetamidothiazol-4-yl)-2-methoxyiminoacetamido]-4-methylthio-2-oxoazetidine-1-sulfonate in 4 ml of water is added under ice-cooling 0.044 g of sodium monomethyldithiocarbamate, and the mixture is stirred for one hour at room temperature. The same procedure as Example 3B yields 0.057 g of sodium (3R,4S)-3-[2-(2-aminothiazol-4-yl)-2-methoxyiminoacetamido]-4-methylthio-2-oxoazetidine-1-sulfonate.

출처 및 근거

ORD 기록
ord-5e16aed600a146bea3379525f93aea0a
출처 데이터셋
uspto-grants-1989_04
특허 번호
US04822788

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