Chlorotrimethylsilane → Silane, 2,4-cyclopentadien-1-ylidenebis(trimethyl-

HRID 622867

반응식

HRID 622867 반응식
[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[Na+].Cl[Si:8]([CH3:11])([CH3:10])[CH3:9]>O1CCCC1>[CH3:9][Si:8]([C:1]1([Si:8]([CH3:11])([CH3:10])[CH3:9])[CH:5]=[CH:4][CH:3]=[CH:2]1)([CH3:11])[CH3:10].[CH3:9][Si:8]([C:1]1[CH2:5][CH:4]=[CH:3][CH:2]=1)([CH3:11])[CH3:10]

참가 물질

5

반응물 2

HCID 6397ChlorotrimethylsilaneHCID 78681Sodium, 2,4-cyclopentadien-1-yl-

생성물 2

HCID 141813Silane, 2,4-cyclopentadien-1-ylidenebis(trimethyl-HCID 120246731,3-Cyclopentadiene, (trimethylsilyl)-

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

Trimethylsilylcyclopentadiene and bis(trimethylsilyl)cyclopentadiene are prepared by the procedures of Kraihanzel et al., J. Amer. Chem. Soc., 90, 4701 (1968) and I. M. Pribytkova et al., J. of Organometallic Chem., 30, C57-C60 (1971). Sodium cyclopentadienide (44 g, 0.50 mole) is added to 150 ml of tetrahydrofuran. Chlorotrimethylsilane (54 g, 0.5 mole) is added dropwise slowly to the reaction and the stirring is continued for 3 hours. The reaction mixture is poured into 150 ml of cold, distilled water and trimethylsilylcyclopentadiene is extracted into diethyl ether. The extract is rotary evaporated to remove the ethereal solvent and the residue is vacuum distilled to give trimethylsilylcyclopentadiene, b.p. 41° C.-43° C. (16 mm).

후처리

  1. additionThe reaction mixture is poured into 150 ml of cold,
  2. distillationdistilled water and trimethylsilylcyclopentadiene
  3. extractionis extracted into diethyl ether
  4. customThe extract is rotary evaporated
  5. customto remove the ethereal solvent
  6. distillationdistilled

출처 및 근거

ORD 기록
ord-d42af2836cdc4d4a91d217596954d8b4
출처 데이터셋
uspto-grants-1988_09
특허 번호
US04772734

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