Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Phosphorus oxychloride → 11-Chlorodibenzo(b,f)(1,4)thiazepine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Phosphorus oxychloride | HCID 24813 | — |
| 반응물 | Dibenzothiazepinone | HCID 374829 | — |
| 생성물 | 11-Chlorodibenzo(b,f)(1,4)thiazepine | HCID 10586481 | — |
반응 단계
A solution of dibenzo[b,f][1,4]thiazepin-11(10H)-one, prepared as described in the previous step, (14.6 g, 64 mmol) in phosphorus oxychloride (20 mL) was heated to reflux for 2 hours. The mixture was concentrated to provide the crude product which was used directly without further purification. ESI-MS (M+1): 246 calc. for C13H8ClNS 245.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09304126B2 |
| 출처 데이터셋 | uspto-grants-2016_04 |
| ORD ID | ord-5495f8c0b4b64c369589c5d5e38250a4 |
| 출처 메모 | uspto-grants-2016_04 |