참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Diphenyl Ether | HCID 7583 | — |
| 반응물 | Triphenylbismuth | HCID 11774 | — |
| 반응물 | Trioctylphosphine | HCID 20851 | — |
| 반응물 | Trioctylphosphine oxide | HCID 65577 | — |
| 반응물 | Oleic Acid | HCID 445639 | — |
| 반응물 | Oleylamine | HCID 5356789 | — |
| 반응물 | Selenium | HCID 6326970 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Toluene | HCID 1140 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 용매 | 1-Octadecene | HCID 8217 | — |
| 용매 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 생성물 | Di-n-octylphosphinic acid | HCID 99411 | — |
반응 단계
Materials. 1-methyl-2-pyrrolidinone (99.5%, Aldrich), 1-octadecene (90%, Aldrich), acetonitrile (99.9%, Fisher Chemical), triphenylbismuth (99%, Strem), CdO (99.5%, Aldrich), diphenyl ether (99%, Aldrich), methanol (ACS grade, VWR), oleic acid (90%, Aldrich), oleylamine (70% Aldrich), selenium (99.99%, Strem), trioctylphosphine (90%, Aldrich), trioctylphosphine oxide (99%, Strem), toluene (ACS grade, VWR). 0.2M Se-ODE was prepared by dissolving selenium powder in 1-octadecene at 200° C. for 2 hr under inert atmosphere according to the procedure by Bullen et al.[42]; trioctylphosphine oxide (TOPO) was recrystallized from acetonitrile prior to use; di-n-octylphosphinic acid (DOPA) was synthesized according to the procedure reported by Wang et al.[1]; a stock suspension of 2 mM triphenylbismuth (BiPh3) in 1-octadecene was prepared in advance.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09306110B2 |
|---|
| 출처 데이터셋 | uspto-grants-2016_04 |
|---|
| ORD ID | ord-9c3a268df10549b2be3b6aeb3d49fbb1 |
|---|
| 출처 메모 | uspto-grants-2016_04 |
|---|
