Ammonia → Ammonia

HRID 6276

반응식

HRID 6276 반응식
[NH3:1].[C:2](#[N:5])[CH:3]=[CH2:4]>O>[NH3:5].[C:2](#[N:5])[CH:3]=[CH2:4].[NH2:5][CH2:2][CH2:3][C:4]#[N:1].[C:2]([CH2:3][CH2:4][NH:1][CH2:4][CH2:3][C:2]#[N:5])#[N:5]

참가 물질

7

반응물 2

HCID 222Ammonia3회HCID 7855Acrylonitrile2회

생성물 4

HCID 222AmmoniaHCID 16473-AminopropionitrileHCID 7855AcrylonitrileHCID 81493,3'-Iminodipropionitrile

시약·촉매·용매 1

HCID 962Water용매

실험 절차

It is also known that the addition of protic solvents has an advantageous effect on the addition reaction of NH3 with acrylonitrile. The addition of steam to the mixture of acrylonitrile and ammonia is disclosed in, for example, Chem. Abstr. Vol. 83, 26879. Usually, however, aqueous ammonia is used in the temperature range from 80° to 130° C. With a ratio of ammonia to acrylonitrile to water of 5-15:1:5-20, 3-aminopropionitrile is obtained, in addition to bis(2-cyanoethyl)amine, in yields of from 57 to 80% (eg. U.S. Pat. No. 3,935,256--62%, DE-A-24 36 651--70%, U.S. Pat. No. 2,448,013--78%, U.S. Pat. No. 2,819,903--59%, Org. Syn. (1947), 27, 3 to 5 - 57%). The disadvantages of these processes using aqueous ammonia arise in the working up or further processing of the product mixture:

후처리

  1. additionIt is also known that the addition of protic solvents
  2. additionThe addition of steam
  3. customis used in the temperature range from 80° to 130° C

출처 및 근거

ORD 기록
ord-994fe399445642c1ae38540975c70fa4
출처 데이터셋
uspto-grants-1993_09
특허 번호
US05247120

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