Sodium hexafluoroantimonate → HCID 19734742, 화합물

HRID 6285노트

반응식

F[B-](F)(F)F.[CH3:6][C:7]1[CH:30]=[CH:29][C:10]([CH2:11][S+:12]([CH2:21][C:22]2[CH:27]=[CH:26][C:25]([CH3:28])=[CH:24][CH:23]=2)[CH2:13][C:14]2[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][CH:15]=2)=[CH:9][CH:8]=1.[F:31][Sb-:32]([F:37])([F:36])([F:35])([F:34])[F:33].[Na+]>>[F:31][Sb-:32]([F:37])([F:36])([F:35])([F:34])[F:33].[CH3:20][C:17]1[CH:18]=[CH:19][C:14]([CH2:13][S+:12]([CH2:11][C:10]2[CH:9]=[CH:8][C:7]([CH3:6])=[CH:30][CH:29]=2)[CH2:21][C:22]2[CH:27]=[CH:26][C:25]([CH3:28])=[CH:24][CH:23]=2)=[CH:15][CH:16]=1

참가 물질

반응물 2

HCID 16689647Sodium hexafluoroantimonate

HCID 19795292Tris(p-methylbenzyl)sulfonium tetrafluoroborate

생성물 1

HCID 19734742HCID 19734742, 화합물수율 87.3%

실험 절차

Analogously to Example 4c), 100 g (230 mmol) of tris(p-methylbenzyl)sulfonium tetrafluoroborate are reacted with 119.0 g (460 mmol) of sodium hexafluoroantimonate. Recrystallization in isopropanol gives 117.1 g (87% of theory) of tris(p-methylbenzyl)sulfonium hexafluoroantimonate in the form of white crystals of melting point 88°-91° C.

후처리

customRecrystallization in isopropanol

출처 및 근거

ORD 기록: ord-dcb6757025c842f682ae2753a298d10d
출처 데이터셋: uspto-grants-1993_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05247113

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