Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,6-Diphenylphenol → 2,2-Bis(trifluoromethylsulfonyl)ethyl-2,6-diphenylphenol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,6-Diphenylphenol | HCID 75512 | — |
| 반응물 | 1,1,3,3-Tetrakis(trifluoromethanesulfonyl)propane | HCID 20471422 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | 2,2-Bis(trifluoromethylsulfonyl)ethyl-2,6-diphenylphenol | HCID 86712044 | 97% |
반응 단계
1,1,3,3-Tetrakis(trifluoromethylsulfonyl)propane [4] (157.3 mg, 0.28 mmol) was added to an acetonitrile (0.25 ml) solution of 2,6-diphenylphenol (61.9 mg, 0.25 mmol) at room temperature. After 9 hours of stirring, it was purified by Kugelrohr distillation (120° C./3 mmHg) thereby obtaining 4-(2,2-bis(trifluoromethylsulfonyl)ethyl-2,6-diphenylphenol [1n] with a yield of 97% (130.7 mg, 0.24 mmol).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09314782B2 |
| 출처 데이터셋 | uspto-grants-2016_04 |
| ORD ID | ord-848fe28437874a8395a0f0132f1f7fd1 |
| 출처 메모 | uspto-grants-2016_04 |