Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Chlorbenside → 4-Chlorophenylbis(4-chlorobenzyl)sulfonium tetrafluoroborate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Chlorbenside | HCID 7639 | — |
| 반응물 | 4-Chlorobenzyl alcohol | HCID 13397 | — |
| 반응물 | Tetrafluoroboric acid | HCID 28118 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 4-Chlorophenylbis(4-chlorobenzyl)sulfonium tetrafluoroborate | HCID 19795301 | 77.4% |
반응 단계
5.2 g (19.4 mmol) of 4-chlorophenyl 4-chlorobenzyl sulfide, 4.14 g (29.0 mmol) of 4-chlorobenzyl alcohol and 14.15 g (87 mmol) of hydrogen tetrafluoroborate (54% in diethyl ether) in 20 ml of methylene chloride are reacted as in Example 6a) to give 7.23 g (77.4% of theory) of 4-chlorophenylbis(4-chlorobenzyl)sulfonium tetrafluoroborate in the form of white-beige crystals of melting point 147°-148° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05247113 |
| 출처 데이터셋 | uspto-grants-1993_09 |
| ORD ID | ord-97f55f6466014133b0ecc5caef9de86e |
| 출처 메모 | uspto-grants-1993_09 |