Potassium Butyltrifluoroborate → HCID 118228972, 화합물

HRID 629152노트

반응식

HRID 629152 반응식
Br[C:2]1[CH:12]=[CH:11][C:5]2[CH:6]=[C:7]([CH:9]=[O:10])[S:8][C:4]=2[CH:3]=1.[CH2:13]([B-](F)(F)F)[CH2:14][CH2:15][CH3:16].[K+]>>[CH2:13]([C:2]1[CH:12]=[CH:11][C:5]2[CH:6]=[C:7]([CH:9]=[O:10])[S:8][C:4]=2[CH:3]=1)[CH2:14][CH2:15][CH3:16]

참가 물질

3

반응물 2

HCID 23693579Potassium ButyltrifluoroborateHCID 568323096-Bromobenzo[b]thiophene-2-carbaldehyde

생성물 1

HCID 118228972HCID 118228972, 화합물수율 85.6%

실험 절차

The compound was synthesized as in Example 3.1 using 6-bromobenzothiophene-2-carbaldehyde (110 mg, 0.46 mmol) in place of 5-bromo-2-formylfuran and potassium butyltrifluoroborate (113 mg, 0.69 mmol) in place of hexylboronic acid to give 6-butylbenzothiophene-2-carbaldehyde (86 mg, 78%). Used without further characterization.

출처 및 근거

ORD 기록
ord-a10f8938f6d14aba9c21514ed39a5f30
출처 데이터셋
uspto-grants-2016_04
특허 번호
US09315495B2

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