4-Methoxyphenol → 4-Methoxycyclohexanol (cis,trans)

HRID 633520

반응식

HRID 633520 반응식
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][CH:4]=1>C(O)(=O)C.[Pt]=O>[CH3:1][O:2][CH:3]1[CH2:8][CH2:7][CH:6]([OH:9])[CH2:5][CH2:4]1

참가 물질

4

반응물 1

HCID 90154-Methoxyphenol

생성물 1

HCID 1403324-Methoxycyclohexanol (cis,trans)

시약·촉매·용매 2

HCID 82844Platinum oxide (PtO)촉매HCID 176Acetic Acid용매

반응 조건

온도
50 °C

실험 절차

A mixture of 4-methoxyphenol (0.10 g, 0.806 mmol) in acetic acid (10 mL) was added to platinum oxide (0.020 g, 0.088 mmol) in a 50 mL pressure bottle and heated at 50° C. under hydrogen at 30 psi for 1 hour. The solid was removed by filtration, and the filtrate was concentrated to provide the title compound.

후처리

  1. customThe solid was removed by filtration
  2. concentrationthe filtrate was concentrated

출처 및 근거

ORD 기록
ord-2dc8bd4942754b03ab5ddc5dbd1b51dd
출처 데이터셋
uspto-grants-2016_04
특허 번호
US09321764B2

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