Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cyclopropanecarboxylic acid, 1-cyano-2-ethenyl-, ethyl ester → (5-Benzyl-3-furyl)methyl 2-vinyl-1-cyanocyclopropane-1-carboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cyclopropanecarboxylic acid, 1-cyano-2-ethenyl-, ethyl ester | HCID 564450 | — |
| 반응물 | 3-Furanmethanol, 5-(phenylmethyl)- | HCID 12364396 | — |
| 생성물 | (5-Benzyl-3-furyl)methyl 2-vinyl-1-cyanocyclopropane-1-carboxylate | HCID 20256455 | 85.9% |
반응 단계
In a manner similar to that described above, a transalcoholysis reaction was carried out using ethyl 2-vinyl-1-cyanocyclopropane-1-carboxylate and (5-benzyl-3-furyl)carbinol. The ratio of reactants, catalyst level, and reaction temperature employed were the same as indicated in Example II. (5-Benzyl-3-furyl)methyl 2-vinyl-1-cyanocyclopropane-1-carboxylate was obtained in 85.9% yield and purified by separation using the liquid chromatographic procedure. The structure of the purified (99.4%) product was confirmed by mass spectroscopy and nuclear magnetic resonance spectroscopy.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04556409 |
| 출처 데이터셋 | uspto-grants-1985_12 |
| ORD ID | ord-514e208e17814541847675ad930cd0ec |
| 출처 메모 | uspto-grants-1985_12 |