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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 637247생성일: 2026년 10월 25일

Cyclopropanecarboxylic acid, 1-cyano-2-ethenyl-, ethyl ester → (5-Benzyl-3-furyl)methyl 2-vinyl-1-cyanocyclopropane-1-carboxylate

https://huagongshe.com/reaction/637247

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참여 물질

역할이름HCID투입량
반응물Cyclopropanecarboxylic acid, 1-cyano-2-ethenyl-, ethyl esterHCID 564450—
반응물3-Furanmethanol, 5-(phenylmethyl)-HCID 12364396—
생성물(5-Benzyl-3-furyl)methyl 2-vinyl-1-cyanocyclopropane-1-carboxylateHCID 2025645585.9%

반응 단계

In a manner similar to that described above, a transalcoholysis reaction was carried out using ethyl 2-vinyl-1-cyanocyclopropane-1-carboxylate and (5-benzyl-3-furyl)carbinol. The ratio of reactants, catalyst level, and reaction temperature employed were the same as indicated in Example II. (5-Benzyl-3-furyl)methyl 2-vinyl-1-cyanocyclopropane-1-carboxylate was obtained in 85.9% yield and purified by separation using the liquid chromatographic procedure. The structure of the purified (99.4%) product was confirmed by mass spectroscopy and nuclear magnetic resonance spectroscopy.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04556409
출처 데이터셋uspto-grants-1985_12
ORD IDord-514e208e17814541847675ad930cd0ec
출처 메모uspto-grants-1985_12