Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethylformamide → 6-(6-Hydroxyhexyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | 6-(6-Hydroxyhexyl)-2,3-dimethoxy-5-methylphenol | HCID 20254619 | — |
| 촉매 | Salcomine | HCID 26517 | — |
| 용매 | Oxygen | HCID 977 | — |
| 생성물 | 6-(6-Hydroxyhexyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone | HCID 12881463 | — |
반응 단계
To a dimethylformamide solution (20 ml) of 6-(6-hydroxyhexyl)-2,3-dimethoxy-5-methylphenol (1.5 g) is added bis(salicylidene)ethylenediiminocobalt(II) (15 mg), and the mixture is stirred in oxygen streams at atmospheric temperature and pressure for 72 hours. The reaction product is isolated as in Example 7 and purified by silica gel column chromatography. The ether-hexane (1:1) eluate yields 6-(6-hydroxyhexyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone (1.1 g) as orange-yellow oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04559177 |
| 출처 데이터셋 | uspto-grants-1985_12 |
| ORD ID | ord-462b9c8a36eb47669301e031c10faa9d |
| 출처 메모 | uspto-grants-1985_12 |