Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethylformamide → 6-(12-Acetoxydodecyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | 6-(12-Acetoxydodecyl)-2,3-dimethoxy-5-methylphenol | HCID 13065236 | — |
| 촉매 | Salcomine | HCID 26517 | — |
| 용매 | Oxygen | HCID 977 | — |
| 생성물 | 6-(12-Acetoxydodecyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone | HCID 12881465 | — |
반응 단계
To a dimethylformamide solution (20 ml) of 6-(12-acetoxydodecyl)-2,3-dimethoxy-5-methylphenol (1.1 g) is added bis(salicylidene)ethylenediiminocobalt(II) (40 mg) and the mixture is stirred in oxygen streams at atmospheric pressure and temperature for 72 hours. The product is isolated as in Example 7 and recrystallized from etherhexane (1:1). The above procedure yields 6-(12-acetoxydodecyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone (0.84 g) as orange-yellow needles melting at 47° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04559177 |
| 출처 데이터셋 | uspto-grants-1985_12 |
| ORD ID | ord-9d0c04129eaa4c1dac08bb09ea2adde5 |
| 출처 메모 | uspto-grants-1985_12 |