Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dimethylformamide → HCID 12881466, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dimethylformamide | HCID 6228 | — |
| 반응물 | 6-(20-Hydroxyeicosyl)-2,3-dimethoxy-5-methylphenol | HCID 12832663 | — |
| 촉매 | Salcomine | HCID 26517 | — |
| 용매 | Oxygen | HCID 977 | — |
| 생성물 | HCID 12881466 | HCID 12881466 | — |
반응 단계
To a dimethylformamide solution (50 ml) of 6-(20-hydroxyeicosanyl)-2,3-dimethoxy-5-methylphenol (4.0 g) is added bis(salicylidene)ethylenediiminocobalt(II) (40 mg), and the mixture is stirred in oxygen streams at atmospheric temperature and pressure for 72 hours. The product is isolated as in Example 7 and recrystallized from ether. The above procedure yields 6-(20-hydroxyeicosyl)-2,3-dimethoxy-5-methyl-1,4-benzoquinone (3.28 g) as yellow needles melting at 85° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04559177 |
| 출처 데이터셋 | uspto-grants-1985_12 |
| ORD ID | ord-2c2f900c296845b9b095355b03bb20c7 |
| 출처 메모 | uspto-grants-1985_12 |