Nitric Acid → HCID 54574717, 화합물

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[CH3:1][CH:2]([CH2:5][CH2:6][CH3:7])[CH:3]=[CH2:4].[N+:8]([O-])([OH:10])=[O:9]>>[CH3:1][C:2]([CH2:5][CH2:6][CH3:7])=[CH:3][CH2:4][N+:8]([O-:10])=[O:9]

참가 물질

반응물 2

HCID 944Nitric Acid

HCID 188483-Methyl-1-hexene

생성물 1

HCID 54574717HCID 54574717, 화합물

반응 조건

온도: 65 °C

실험 절차

3-Methyl-1-hexene (22.2 mL, 0.15 moles) was mixed with concentrated nitric acid (18 mL, 0.28 moles) at room temperature. With rapid stirring the solution was heated to 65° C. for 3 hours. The heat was removed and the solution stirred an additional 30 min. The organic layer was separated and washed with a saturated sodium chloride solution (3×15 mL) then dried over magnesium sulfate. Vacuum distillation (20 Torr, 28° C.) removed unreacted 3-methyl-1-hexene. A yellow oil remained. Gas chromatography and IR spectroscopy indicate both cis- and trans-3-methyl-1-nitro-2-hexene are present along with a small amount of 1-nitro-2-hexanol. These structures were confirmed by IR and GC analysis.

후처리

customThe heat was removed
stirringthe solution stirred an additional 30 min
customThe organic layer was separated
washwashed with a saturated sodium chloride solution (3×15 mL)
dry with materialthen dried over magnesium sulfate
distillationVacuum distillation (20 Torr, 28° C.)
customremoved unreacted 3-methyl-1-hexene

출처 및 근거

ORD 기록: ord-fcc005098f274feaa1364c2902050e3f
출처 데이터셋: uspto-grants-1985_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04561862

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