Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzene → Allyl glycidyl fumarate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzene | HCID 241 | — |
| 반응물 | Perpropionic acid | HCID 65136 | — |
| 반응물 | Diallyl fumarate | HCID 5355330 | — |
| 생성물 | Allyl glycidyl fumarate | HCID 22034851 | — |
반응 단계
9.8 kg (50 mol) of diallyl fumarate were reacted with 26.18 kg of a 22% strength solution of perpropionic acid in benzene (64 mol) at 60° C. in a manner analogous to that described in Example 1. After a reaction time of 6.8 hours, a percarboxylic acid conversion of 96.8% resulted. The conversion of diallyl fumarate was 90%. Allyl glycidyl fumarate was formed with a selectivity of 46.2% and diglycidyl fumarate was formed with a selectivity of 42.3%, in each case based on the diallyl fumarate reacted.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04562274 |
| 출처 데이터셋 | uspto-grants-1985_12 |
| ORD ID | ord-a2318753c1474807a85d88147d159cd1 |
| 출처 메모 | uspto-grants-1985_12 |