Benzene → HCID 20253115, 화합물

HRID 638658

반응식

HRID 638658 반응식
[CH2:1]([N:4]1[C:8](=[O:9])[N:7]([CH2:10][CH:11]=[CH2:12])[N:6]([CH2:13][CH:14]=[CH2:15])[C:5]1=[O:16])[CH:2]=[CH2:3].CCC(OO)=[O:20].C1C=CC=CC=1>>[CH2:1]([N:4]1[C:5](=[O:16])[N:6]([CH2:13][CH:14]2[O:20][CH2:15]2)[N:7]([CH2:10][CH:11]=[CH2:12])[C:8]1=[O:9])[CH:2]=[CH2:3]

참가 물질

4

반응물 3

HCID 241BenzeneHCID 65136Perpropionic acidHCID 20253124HCID 20253124, 화합물2회

생성물 1

HCID 20253115HCID 20253115, 화합물

실험 절차

6.895 kg (35 mol) of trisallylurazole were reacted with 31.5 kg of a 22% strength solution of perpropionic acid in benzene (77 mol) at 60° C. in a manner analogous to that described in Example 1. After a reaction time of 10 hours, the percarboxylic acid conversion was 97.2% and the conversion of trisallylurazole was 94.6%. Diallylglycidylurazole was formed in a selectivity of 28.3%, allyldiglycidylurazole was formed in a selectivity of 41.2% and trisglycidylurazole was formed with a selectivity of 20.1%, in each case based on the trisallylurazole reacted.

후처리

  1. customAfter a reaction time of 10 hours

출처 및 근거

ORD 기록
ord-0a2156b74f054fd0b919e929ccd536e7
출처 데이터셋
uspto-grants-1985_12
특허 번호
US04562274

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