Benzene → Diallylglycidylurazole
반응식
[CH2:1]([N:4]1[C:8](=[O:9])[N:7]([CH2:10][CH:11]=[CH2:12])[N:6]([CH2:13][CH:14]=[CH2:15])[C:5]1=[O:16])[CH:2]=[CH2:3].CCC(OO)=[O:20].C1C=CC=CC=1>>[CH2:1]([N:4]1[C:5](=[O:16])[N:6]([CH2:13][CH:14]2[O:20][CH2:15]2)[N:7]([CH2:10][CH:11]=[CH2:12])[C:8]1=[O:9])[CH:2]=[CH2:3]참가 물질
4
실험 절차
6.895 kg (35 mol) of trisallylurazole were reacted with 31.5 kg of a 22% strength solution of perpropionic acid in benzene (77 mol) at 60° C. in a manner analogous to that described in Example 1. After a reaction time of 10 hours, the percarboxylic acid conversion was 97.2% and the conversion of trisallylurazole was 94.6%. Diallylglycidylurazole was formed in a selectivity of 28.3%, allyldiglycidylurazole was formed in a selectivity of 41.2% and trisglycidylurazole was formed with a selectivity of 20.1%, in each case based on the trisallylurazole reacted.
후처리
- customAfter a reaction time of 10 hours