Sodium dithiobenzoate → Bis(thiobenzoyl) Disulfide

HRID 640033

반응식

HRID 640033 반응식
[C:1]([S-:9])(=[S:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Na+]>O.[Fe-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]>[C:1]([S:9][S:9][C:1](=[S:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)(=[S:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

참가 물질

4

반응물 1

HCID 11030352Sodium dithiobenzoate2회

생성물 1

HCID 10902862Bis(thiobenzoyl) Disulfide

시약·촉매·용매 2

HCID 178511488HCID 178511488, 화합물촉매2회HCID 962Water용매

실험 절차

Potassium ferricyanide (III) (32.93 g) was dissolved in deionized water (500.0 mL). Sodium dithiobenzoate solution (350.0 mL) was transferred to a 1 L conical flask equipped with a magnetic stir bar. Potassium ferricyanide solution was added drop wise to the sodium dithiobenzoate via an addition funnel over a period of one hour under vigorous stirring. The red precipitate was filtered and washed with deionized water until the washings become colorless. The solid was dried in vacuum at room temperature overnight; the product was recrystallized from ethanol.

후처리

  1. customequipped with a magnetic stir bar
  2. filtrationThe red precipitate was filtered
  3. washwashed with deionized water until the washings
  4. customThe solid was dried in vacuum at room temperature overnight
  5. customthe product was recrystallized from ethanol

출처 및 근거

ORD 기록
ord-061b854e51fb4b27ae210ae02eac35d1
출처 데이터셋
uspto-grants-2010_04
특허 번호
US07691937B2

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