6-Isopropoxy-3,4-dihydro-2H-naphthalen-1-one → HCID 68578523, 화합물

반응식

[CH:1]([O:4][C:5]1[CH:6]=[C:7]2[C:12](=[CH:13][CH:14]=1)[C:11](=O)[CH2:10][CH2:9][CH2:8]2)([CH3:3])[CH3:2].[CH3:16][Mg]I>>[CH:1]([O:4][C:5]1[CH:6]=[C:7]2[C:12]([C:11]([CH3:16])=[CH:10][CH2:9][CH2:8]2)=[CH:13][CH:14]=1)([CH3:3])[CH3:2]

참가 물질

반응물 2

HCID 27594756-Isopropoxy-3,4-dihydro-2H-naphthalen-1-one

HCID 178418373HCID 178418373, 화합물

생성물 1

HCID 68578523HCID 68578523, 화합물

실험 절차

Using general procedure A (Exp. 1.1), 6-isopropoxy-3,4-dihydro-2H-naphthalen-1-one was reacted with MeMgI to give 7-isopropoxy-4-methyl-1,2-dihydro-naphthalene as a colorless oil. MS: 203.4 ([M+H]+).

출처 및 근거

ORD 기록: ord-e67cddd9ddb7445f822ebee537ae5466
출처 데이터셋: uspto-grants-2010_04
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07696240B2

반응 노트

불러오는 중…