Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Octanal → 2-Benzoyl-dec-2-enoic acid ethyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Octanal | HCID 454 | — |
| 반응물 | Ethyl benzoylacetate | HCID 7170 | — |
| 반응물 | Piperidine | HCID 8082 | — |
| 용매 | tert-Butyl methyl ether | HCID 15413 | — |
| 생성물 | 2-Benzoyl-dec-2-enoic acid ethyl ester | HCID 68840145 | — |
반응 단계
Piperidine (0.10 ml, 0.5 mol %) is added to a mixture of octanal (25.6 g, 0.20 mol) and ethyl benzoylacetate (38.4 g, 0.20 mol) at 5° C. The resulting solution is warmed to room temperature and stirred for 24 h, during which a fine emulsion is formed. The mixture is diluted with methyl t-butyl ether and the organic layer washed with 2 N aq. HCl-solution, water and brine, then dried over MgSO4.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09447364B2 |
| 출처 데이터셋 | uspto-grants-2016_09 |
| ORD ID | ord-d130adbbc50d4bb7b96cde2778db0c2d |
| 출처 메모 | uspto-grants-2016_09 |