Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl mercaptan → 2-Benzylthio-4-(2-chloro-4-trifluoromethylphenoxy)nitrobenzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl mercaptan | HCID 7509 | — |
| 반응물 | Sodium hydride | HCID 24758 | — |
| 반응물 | Benzene, 2-chloro-1-(3,4-dinitrophenoxy)-4-(trifluoromethyl)- | HCID 156238 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | 2-Benzylthio-4-(2-chloro-4-trifluoromethylphenoxy)nitrobenzene | HCID 20236281 | — |
반응 단계
1.7 g of benzyl mercaptan was dissolved in dry tetrahydrofuran and 0.5 g of sodium hydride added with stirring under dry nitrogen. The reaction mixture was stirred under reflux for 30 minutes, and a solution of 5 g of 1A dissolved in 25 ml of dry tetrahydrofuran was added dropwise. Reaction occurred rapidly, and the product was chromatographically purified to give 2-benzylthio-4-(2-chloro-4-trifluoromethylphenoxy)nitrobenzene (1B) as a yellow oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04609394 |
| 출처 데이터셋 | uspto-grants-1986_09 |
| ORD ID | ord-a90262bdbc264b34851ba14fae0a069f |
| 출처 메모 | uspto-grants-1986_09 |