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Mandelic Acid → O-(alpha-Phenyl-beta-mercaptopropanoyl)mandelic acid

HRID 64914
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HRID 64914 반응식
C(S[CH2:5][CH2:6][C:7]([OH:9])=O)(=O)C.[C:10]([OH:20])(=[O:19])[CH:11]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)[OH:12].[CH:21]1[CH:26]=[CH:25][C:24](C[C@H](O)C(O)=O)=[CH:23][CH:22]=1.C([S:36]CC(C1C=CC=CC=1)C(OC(=O)C(C1C=CC=CC=1)O)=O)(=O)C>>[C:21]1([C:7](=[O:9])[C:6]([O:19][C:10](=[O:20])[CH:11]([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[OH:12])([SH:36])[CH3:5])[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1
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참가 물질

5

반응물 4

HCID 1292Mandelic AcidHCID 2627193-(Acetylthio)propionic AcidHCID 4447183-Phenyllactic acid, (S)-HCID 88674951O-[3-(acetylthio)-2-phenylpropanoyl]mandelic acid

생성물 1

HCID 131714854O-(alpha-Phenyl-beta-mercaptopropanoyl)mandelic acid

실험 절차

By substituting 3-(acetylthio)-2-phenylpropanoic acid for 3-(acetylthio)propanoic acid and mandelic acid for L-3-phenyllactic acid in the procedure of Example 5 and then submitting the product to the procedure of Example 6, O-[3-(acetylthio)-2-phenylpropanoyl]mandelic acid and the title compound is obtained.

출처 및 근거

ORD 기록
ord-3b7fd876d48c4b59a8f9ecf5fc329a81
출처 데이터셋
uspto-grants-1986_09
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US04611002

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