Potassium Cyanide → HCID 13713134, 화합물

HRID 64918

반응식

HRID 64918 반응식
[Br:1][C:2]([Br:12])=[CH:3][C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[CH:7]=[O:8].[C-:13]#[N:14].[K+].[Cl:16][C:17]([Cl:27])=[CH:18][CH:19]1[CH:21]([C:22](Cl)=[O:23])[C:20]1([CH3:26])[CH3:25]>CCOCC.O.[Cl-].C([N+](CC)(CC)CC1C=CC=CC=1)C>[Cl:16][C:17]([Cl:27])=[CH:18][CH:19]1[CH:21]([C:22]([O:8][CH:7]([C:13]#[N:14])[C:6]2[CH:9]=[CH:10][CH:11]=[C:4]([CH:3]=[C:2]([Br:12])[Br:1])[CH:5]=2)=[O:23])[C:20]1([CH3:26])[CH3:25]

참가 물질

7

반응물 3

HCID 9032Potassium CyanideHCID 94551Permethric chlorideHCID 13713133HCID 13713133, 화합물

생성물 1

HCID 13713134HCID 13713134, 화합물

시약·촉매·용매 3

HCID 66133Benzyl triethylammonium chloride촉매HCID 962Water용매HCID 3283Diethyl Ether용매

실험 절차

In a two-phase reaction mixture, 6.1 g (0.021 mole) of 3-(2,2-dibromovinyl)-benzaldehyde in 50 ml of ether, 1.5 g (0.023 mole) of KCN in 20 ml of water, 5.0 g (0.022 mole) of 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid chloride and 0.5 g of triethylbenzylammonium chloride are stirred at room temperature, and thorough mixing is continued overnight at 25° C. The phases are separated and the aqueous phase is extracted twice by shaking with ether. The ether solution is washed with sodium bisulfite, NaHCO3 and water, dried over Na2SO4 and evaporated down.

후처리

  1. additionthorough mixing
  2. customThe phases are separated
  3. extractionthe aqueous phase is extracted twice
  4. washThe ether solution is washed with sodium bisulfite, NaHCO3 and water
  5. dry with materialdried over Na2SO4
  6. customevaporated down

출처 및 근거

ORD 기록
ord-3e225933de294529b6d2ce55ae8f2e32
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04611010

연결된 노트

불러오는 중…