Phthaloyl chloride → 2-Methoxyanthraquinone

HRID 649279

반응식

HRID 649279 반응식
[C:1]1([O:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:9](Cl)(=[O:19])[C:10]1[C:11](=[CH:15][CH:16]=[CH:17][CH:18]=1)[C:12](Cl)=[O:13]>>[CH3:8][O:7][C:1]1[CH:6]=[CH:5][C:4]2[C:12](=[O:13])[C:11]3[C:10](=[CH:18][CH:17]=[CH:16][CH:15]=3)[C:9](=[O:19])[C:3]=2[CH:2]=1

참가 물질

3

반응물 2

HCID 6955Phthaloyl chlorideHCID 7519Anisole

생성물 1

HCID 186462-Methoxyanthraquinone수율 79.8%

실험 절차

The method was similar to that in Example 1, using 10.8 g (0.1 mols) of anisole and 20.2 g (0.1 mols) of phthalic acid dichloride. The product was 19.0 g (60% yield) of 2-methoxy-9,10-anthraquinone (13), m.p. 195°-197° C.

출처 및 근거

ORD 기록
ord-198ac111e29e4e98950e400ac618c669
출처 데이터셋
uspto-grants-1988_04
특허 번호
US04739062

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