1,1-Dichloro-1-fluoromethanesulfenyl chloride → 2-Methoxy-3-cyano-4-(dichlorofluoromethyl)sulfenyl-5-methylpyrrole

HRID 650268노트

반응식

HRID 650268 반응식
[CH3:1][O:2][C:3]1[NH:4][C:5]([CH3:10])=[CH:6][C:7]=1[C:8]#[N:9].[F:11][C:12]([S:15]Cl)([Cl:14])[Cl:13]>C(Cl)Cl>[CH3:1][O:2][C:3]1[NH:4][C:5]([CH3:10])=[C:6]([S:15][C:12]([Cl:14])([Cl:13])[F:11])[C:7]=1[C:8]#[N:9]

참가 물질

4

반응물 2

HCID 759261,1-Dichloro-1-fluoromethanesulfenyl chlorideHCID 217147462-Methoxy-3-cyano-5-methylpyrrole

생성물 1

HCID 155446192-Methoxy-3-cyano-4-(dichlorofluoromethyl)sulfenyl-5-methylpyrrole

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

A suspension of 2-methoxy-3-cyano-5-methylpyrrole (0.5 g) in 5 ml of CH2Cl2 was treated with Cl2FCSCl (0.45 ml) and stirred at room temperature for 14 h. The resulting precipitate was filtered, washed with CH2Cl2, and dried under high vacuum to afford an off-white solid (0.59 g), m.p. 175° C.

후처리

  1. filtrationThe resulting precipitate was filtered
  2. washwashed with CH2Cl2
  3. customdried under high vacuum

출처 및 근거

ORD 기록
ord-af276a2a619b4f6bbb7ebd9628e774c3
출처 데이터셋
uspto-grants-2001_08
특허 번호
US06271392B1

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